Abstract:
MoO2–reduced graphene oxide composite (MoO2–rGO) acts as the electrode material for all vanadium redox flow battery (VRFB). MoO2–rGO composite exhibits excellent electrocatalytic
redox reversibility for V3+/V2+ and VO2+/VO2+ and larger anodic and cathodic peak currents than
those of other individual MoO2 and rGO samples. The voltage efficiency of the VRFB using
MoO2–rGO nanocomposite at 80 mA cm−2
is 82.14%, which is 4.23% and 13.56% higher than
the VRFBs using the rGO-coated graphite felt electrode and the graphite felt electrode,
respectively. It still shows the voltage efficiencies of 73.83% and 68.50% at 120 mA cm−2
and
140 mA cm−2
, respectively, but other samples have no effective discharge. This improvement is
attributed to the uniform distribution of MoO2 nanoparticles on the rGO surface, avoiding the
restacking of the rGO sheets and suppressing nanoparticle aggregation, which might increase the
effective surface area and improve mass transport at the electrode-electrolyte interface.
Furthermore, oxygen vacancies on MoO2, the high electrical conductivity of rGO, and the high
content of oxygen functional groups act as active sites for the vanadium ion redox reaction.